Matt LeBlanc is getting a little oily in his old age. According to the Daily Star, Matt was at a club in London and was hitting on the woman above. He apparently liked her a lot. A whole lot. The pair were introduced by a mutual friend and the woman, Jo Spyrou says at first Matt was really nice. Jo said that, "He cuddled up to me and said that I smelled nice. He also commented on the dress I was wearing, he really seemed to like it, especially the bits that are cut out which he kept touching."
After every compliment, Matt would ask her to go back to his hotel room and she kept saying no. Finally he decided to pull out his "How you doin'" line from Friends, but forgot it and said, "What you doin?" in his Joey voice. Still did not work and she left soon after saying she felt it would be inappropriate to go to his room.
I don't think you should be surprised. Matt is not exactly above hitting on women in any way possible. While he was married he admitted cheating on his wife with a stripper which led to their divorce. Oh, and he was also probably cheating on his wife with his Joey co-star.